The bizarre oscillating redox reaction between mercury and iron

EXHIBITION-CHEM-250

Source: © Adrian Guy

Demonstrations designed to capture the student's imagination

Redox chemistry, electrode potentials and electrochemical cells are interesting, but can be hard work for sixth form students to understand. This fascinating little demonstration, whilst not the easiest to explain, will always impress your audience.

When an iron nail is placed close the mercury oscillates, 'beats', as if it has a life of its own and you will observe considerable movement or 'beating' if the oscillations are similar to the natural resonant frequency of the droplet. Look more closely and bubbles of gas, relatively rapid oxidation of the nail and fluctuating surface layers of mercury compounds can be seen.

Thanks for using Education in Chemistry. You can view one Education in Chemistry article per month as a visitor. 

A photograph of a teacher standing in a white lab coat, speaking with a class of children in a laboratory, is superimposed on a colourful background. Text reads "Teach Chemistry means support for classroom and staff room".

Register for Teach Chemistry for free, unlimited access

Registration is open to all teachers and technicians at secondary schools, colleges and teacher training institutions in the UK and Ireland.

Get all this, plus much more:

  • unlimited access to resources, core practical videos and Education in Chemistry articles
  • teacher well-being toolkit, personal development resources and online assessments
  • applications for funding to support your lessons

Already a Teach Chemistry member? Sign in now.

Not eligible for Teach Chemistry? Sign up for a personal account instead, or you can also access all our resources with Royal Society of Chemistry membership.