Entertain your students with a series of loud bangs as evolved oxygen increases the rate of burning.
In this exothermic reaction, a series of loud, but harmless, bangs are heard as the oxygen that is evolved increases the rate of burning.
Potassium manganate(VII) powder is sprinkled on to a burning mixture of hydrogen peroxide solution and ethanol. In the exothermic reaction which follows, a series of loud, but harmless, bangs are heard as the oxygen that is evolved increases the rate of burning.
The demonstration is spectacularly noisy, producing sharp, crackling bursts of noise and flame which sometimes seem to build rhythmically. A trial run is recommended for those trying it for the first time.
The demonstration can also be rather messy as splashes of the mixture in the basin are ejected. It is advisable to protect the bench area around the heat resistant mat with some non-flammable, washable material to aid clearing up afterwards.
The demonstration takes about 3 minutes.
For each demonstration:
Evaporating dish (10 cm diameter)
Heat resistant mats
Potassium manganate(VII) (potassium permanganate) (OXIDISING, HARMFUL), 0.5 g
Hydrogen peroxide, 20-volume (IRRITANT), 30 cm3
Ethanol (IDA, Industrial Denatured Alcohol) (HIGHLY FLAMMABLE, HARMFUL), 20 cm3
Refer to Health & Safety and Technical notes section below for additional information.
Health & Safety and Technical notes
Wear eye protection. Use safety screens throughout to protect the audience and the demonstrator. (See CLEAPSS Supplementary Risk Assessment SRA05 on the CLEAPSS website).
Potassium manganate(VII), KMnO4(s), (OXIDISING, HARMFUL, DANGEROUS FOR THE ENVIRONMENT) - see CLEAPSS Hazcard.
Hydrogen peroxide solution, H2O2(aq), (IRRITANT) - see CLEAPSS Hazcard and CLEAPSS Recipe Book.
Ethanol (IDA, Industrial Denatured Alcohol), C2H5OH(l), (HIGHLY FLAMMABLE, HARMFUL) - see CLEAPSS Hazcard.
a Put the evaporating dish on a large heat resistant mat (or use several smaller mats) to protect the bench. Place a safety screen between the mat and the audience.
b Add 30 cm3 of 20-volume hydrogen peroxide solution and 20 cm3 of ethanol to the dish.
c Light the mixture with a burning splint. The ethanol vapour should ignite and burn with an almost invisible flame.
d Now, at arm’s length, sprinkle from a spatula or wooden splint about 0.5 g of potassium manganate(VII) crystals into the dish. Do not sprinkle directly from the bottle.
e Immediately there will be a series of loud bangs, giving the effect of a volley of gunshot and the flames will leap up. The noise will subside into crackling, which can last for up to a minute.
f When the noisy reaction is over, extinguish the burning ethanol (if still alight) by placing a heat resistant mat or tile over the evaporating basin. Do not repeat the demonstration unless you have first rinsed the dish with plenty of water. It can be very difficult to see the ethanol flame under some lighting conditions.
g A residue of brown, solid manganese dioxide will be seen in the evaporating dish – and possibly in the area immediately surrounding it.
Coarse potassium manganate(VII) crystals give fewer but louder bangs, while fine crystals give more but smaller ones.
It is strongly recommended not to use more concentrated solutions of hydrogen peroxide or to alter the other quantities in any other way.
The reaction between manganate(VII) ions and hydrogen peroxide is as follows:
2MnO4–(aq) + 3H2O2(aq) → 2MnO2(s) + 2H2O(l) + 3O2(g) + 2OH–(aq)
The localized evolution of oxygen accelerates the burning of the ethanol, and this produces pockets of evolved energy which manifest themselves in the mini-explosions produced.
Health & Safety checked, 2016
This Practical Chemistry resource was developed by the Nuffield Foundation and the Royal Society of Chemistry.
© Nuffield Foundation and the Royal Society of Chemistry
Page last updated October 2015
This is a resource from the Practical Chemistry project, developed by the Nuffield Foundation and the Royal Society of Chemistry. This collection of over 200 practical activities demonstrates a wide range of chemical concepts and processes. Each activity contains comprehensive information for teachers and technicians, including full technical notes and step-by-step procedures. Practical Chemistry activities accompany Practical Physics and Practical Biology.