Test the melting points of lead, tin and solder to investigate solder as a solid mixture and alloy in this practical

Electric solder is an alloy of tin with one or more other metals. Tin–lead solders were commonly available but now lead-free solders are used for manufacturing, and lead based solders are becoming increasingly difficult to obtain.

In this experiment, students heat samples of tin, lead and tin–lead solder to compare their melting points, observing that the metal alloy has a much lower melting point than either of the pure metals. It shows how such an alloy is more convenient and safer to work with when soldering.

The experiment is conveniently carried out by groups of two and will take about 30 minutes.



  • Eye protection
  • Bunsen burner
  • Tripod
  • Heat resistant mat
  • Pipeclay triangle
  • Crucible lid


  • Tin, a small piece
  • Flux-free solder, a small piece

Health, safety and technical notes

  • Read our standard health and safety guidance.
  • Wear eye protection throughout. Be very careful to avoid coming into contact with molten drops of metal. Ensure good ventilation. It may be advisable for asthmatic students to work in a fume cupboard.
  • Tin, Sn(s) – see CLEAPSS Hazcard HC102A.
  • Flux-free solder – it is important the solder is flux-free. Fumes produced when solder containing rosin-based flux is used, can irritate the respiratory system and in some cases has caused sensitisation.


A diagram of the equipment set-up for comparing melting points of tin, lead and solder in a crucible

Source: Royal Society of Chemistry

How to set up the equipment for melting tin, lead and solder over a Bunsen burner (not pictured)

  1. Place a small piece of tin, lead and solder on an inverted crucible lid. Make sure you know which lump is which!
  2. Place the crucible lid on a pipe clay triangle, on a tripod. Place a lighted Bunsen burner underneath, on a heat resistant mat, and heat the lid gently.
  3. Observe the three lumps to see the order in which they melt.
  4. When all three are molten, turn off the Bunsen burner and allow everything to cool.
  5. Note the order in which the lumps solidify again.

Teaching notes

Remind students of the dangers of coming into contact with hot molten metal.

Good laboratory ventilation is important, particularly if a large number of experiments are being carried out. Asthmatics should be asked to carry out their experiments using a fume cupboard.

A common problem with this experiment is that students forget which lump is which.

The melting points of tin and lead are 232 °C and 328 °C respectively, whilst the solder melts at a lower temperature than either of these. (Lead-free solder tends to melt at about 220°C.) Thus the order of melting is: solder, tin and lead and the order of solidifying is the opposite.

Metal alloys are classified as solid solutions and are usually prepared by mixing together molten metals in an appropriate ratio.

If appropriate to the ability level, students should be asked to compare a conventional solid-liquid solution with that of an alloy.