Explore condensation polymerisation by creating and then investigating the properties of a thermosetting polymer.


Urea is dissolved in aqueous methanal in a throw-away container. Acidification of this solution initiates condensation polymerisation, and a hard, white, thermosetting polymer is formed within a few minutes. After washing, the properties of this substance can be investigated. If a mould is used, the experiment can be extended to show the formation of plastic articles made in a mould by condensation polymerisation.

Lesson organisation

This is a teacher demonstration, taking about 5 minutes for one polymerisation experiment. Extensions to show production of moulded articles will take longer. It should be performed in a fume cupboard to avoid exposure to methanal vapour.

Apparatus Chemicals

The teacher will need:

Eye protection: goggles

Disposable nitrile gloves (for handling the polymer)

Access to a fume cupboard visible to the class

Measuring cylinder, 100 cm3

Throw-away containers with secure lids, at least 2 (Note 1)

Dropping pipette

Glass stirring rod

Object of simple shape for making suitable mould (Note 2)

Bunsen burner (optional)

Tongs (optional)

Quantities for one demonstration:

Methanal solution (formalin), 37 - 40%, (TOXIC), 20 cm(Note 3)

Urea (carbamide), 10 g

Sulfuric acid, concentrated (CORROSIVE),
 1 cm(Note 4)


Aluminium foil

Refer to Health & Safety and Technical notes section below for additional information.

Health & Safety and Technical notes

Read our standard health & safety guidance

Work in a fume cupboard and wear goggles. Wear gloves.when handling the polymer. 

Methanal solution (TOXIC) - see CLEAPSS Hazcard.

Concentrated sulfuric acid (CORROSIVE) - see CLEAPSS Hazcard

Urea - see CLEAPSS Hazcard

1 The container used should be transparent (so the demonstration can be seen), disposable, and preferably should have a secure lid. Used 100 g coffee jars with screw tops are ideal, but any similar size glass or plastic container will do.

2 A mould for casting copies of an object can be made by pressing the object into Plasticene. The object selected should have a simple external shape. Enough Plasticene should be provided to press the shape into, forming a sufficiently substantial mould to retain its shape when handled.

3 Methanal solution (also known as formaldehyde solution, or formalin) should be in good condition. Because the vapour is unpleasant as well as toxic, the supply of this solution for this demonstration should be kept in the fume cupboard, in a stoppered bottle.

4 The acid used should be sulfuric acid, and NOT hydrochloric acid, because of the possibility of forming the carcinogen, bis-chloromethylether.

5 After the demonstration, dispose of the sealed container with the polymer inside as solid waste.


a Dissolve 10 g of urea in 20 cm3 of methanal solution in the disposable container.

b Add about 1 cm3 of concentrated sulfuric acid a drop at a time, using a dropping pipette, and stir steadily. Within a minute the solution begins to go milky and eventually a hard, white solid is formed which is difficult to remove from the container. A lot of heat is evolved.

c Show that the polymer is hard by poking the material with a spatula.

d Wash the polymer thoroughly before passing around the class, as it is likely to be contaminated with unreacted starting materials. Alternatively, pass it round in the container with the lid screwed on.

e Make a plasticene mould from the simple shape and line it with aluminium foil.

f Make another urea-methanal solution as above, but, immediately after adding the acid, pour some of the solution into the mould and allow it to polymerise. Remove from the mould when solid.

g Hold a sample of the polymer (from the mould) with tongs and heat in a Bunsen flame. It will char but not melt, showing that it is a thermosetting polymer.

Teaching notes

The reaction is a condensation polymerisation in which water is eliminated as the hydrogen atoms from the ends of one amino-group from each of two urea molecules combine with the oxygen atom from a methanal molecule. The remaining –CH2– group from the methanal molecule then forms a bridge between two neighbouring urea molecules, as shown below. This process, repeated many thousands of times, forms long chains of urea and methanal molecules linked in this way.

Sometimes the second hydrogen atom on an amino-group will also react with a methanal molecule, producing a branch in the chain, and chains may even become cross-linked to each other. Eventually a random three-dimensional network of cross-linked chains is formed, giving a rigid structure and thus a hard, inflexible material.

The product has many cross links as shown in the diagram below:

Because the tangle of cross-linked chains is almost impossible to separate, the material does not melt on heating, although it will eventually break down at high temperature, decomposing and giving off small molecules such as steam and nitrogen, leaving a charred mass which is largely carbon.

Health & Safety checked, August 2016


This Practical Chemistry resource was developed by the Nuffield Foundation and the Royal Society of Chemistry.

© Nuffield Foundation and the Royal Society of Chemistry

Page last updated September 2016